Lionel Messi has the most career blocked shots per match in LaLiga, with 1.25 per match.

Interpreted as:

most average blocks with a minimum of 15000 min by a player for career

	NAME	SH-BLK/M	MIN	M	START	G	G/M	A	G+A	PK	FK	SH	SOT	WOOD	TCH	TCH-BOX	OFF
1	Lionel Messi L. Messi	1.25	20,544	243	226	231	0.95	95	326	28	28	1,245	591	59	19,689	1,209	87
2	Karim Benzema K. Benzema	0.64	22,041	280	262	166	0.59	72	238	25	1	885	398	41	12,123	1,449	218
3	Vinícius Júnior Vinícius	0.54	16,666	242	183	77	0.32	41	118	7	0	535	240	12	11,099	1,707	107
4	Canales	0.51	19,916	283	224	38	0.13	38	76	8	3	424	136	12	15,810	440	45
5	Iñaki Williams I. Williams	0.48	30,291	407	347	84	0.21	52	136	5	0	783	313	32	13,717	1,700	236
6	Luis Suárez L. Suárez	0.48	20,285	258	229	178	0.69	74	252	14	2	802	389	34	9,765	1,291	304
7	Brais Méndez B. Méndez	0.46	18,517	276	215	42	0.15	29	71	3	3	414	147	9	12,951	545	54
8	Gerard Moreno G. Moreno	0.46	24,695	343	279	131	0.38	38	169	23	0	745	326	25	14,135	1,196	183
9	Isco	0.44	16,095	285	179	47	0.16	51	98	8	1	361	137	8	15,642	529	41
10	Antoine Griezmann A. Griezmann	0.42	30,948	424	359	165	0.39	76	241	12	8	903	401	29	19,290	1,237	201
11	Fabián Orellana F. Orellana	0.42	15,927	200	184	35	0.18	31	66	10	0	349	130	11	11,212	470	54
12	Iago Aspas I. Aspas	0.41	28,332	386	317	158	0.41	60	218	39	7	797	361	31	16,601	1,404	131
13	Raúl García R. García	0.41	19,754	324	220	70	0.22	24	94	19	0	622	229	22	10,980	708	114
14	Mikel Oyarzabal M. Oyarzabal	0.41	25,675	349	293	100	0.29	48	148	32	1	566	240	13	13,003	1,129	138
15	Willian José W. José	0.37	16,004	266	188	82	0.31	26	108	15	2	444	178	8	7,069	563	109
16	José Luis Morales J. Luis Morales	0.36	22,048	332	244	77	0.23	33	110	10	0	496	209	9	10,573	962	118
17	Ante Budimir A. Budimir	0.36	16,294	232	191	95	0.41	10	105	21	0	482	200	15	5,525	997	128
18	Sergi Darder S. Darder	0.33	25,062	326	286	26	0.08	33	59	0	0	386	112	14	15,920	267	13
19	Ángel Correa Á. Correa	0.33	16,451	335	167	68	0.20	41	109	0	0	412	183	11	9,667	1,165	91
20	Luka Modrić L. Modrić	0.32	22,469	327	256	26	0.08	54	80	2	0	321	107	10	22,063	405	17
21	Mauro Arambarri M. Arambarri	0.31	20,796	252	240	22	0.09	12	34	5	1	311	76	12	10,300	296	9
22	Toni Kroos T. Kroos	0.29	23,981	306	277	22	0.07	69	91	0	1	361	118	10	26,536	196	12
23	Casemiro	0.28	16,727	209	192	24	0.11	16	40	0	0	239	61	4	14,776	205	15
24	Saúl	0.28	21,318	317	232	31	0.10	23	54	2	0	374	118	7	15,383	414	44
25	Federico Valverde F. Valverde	0.28	18,140	268	200	25	0.09	30	55	0	1	329	116	7	14,406	339	16

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StatMuse has LaLiga data for shots blocked per match going back to the 2014-15 season.

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	LaLiga	M	W	D	L	GD	PTS
1	Barcelona	38	31	1	6	59	94
2	Real Madrid	38	27	5	6	42	86
3	Villarreal	38	22	6	10	26	72
4	Atlético Madrid	38	21	6	11	18	69
5	Real Betis	38	15	15	8	11	60
6	Celta Vigo	38	14	12	12	5	54
7	Getafe	38	15	6	17	-6	51
8	Rayo	38	12	14	12	-3	50
9	Valencia	38	13	10	15	-9	49
10	Real Sociedad	38	11	13	14	-2	46
11	Espanyol	38	12	10	16	-12	46
12	Athletic Club	38	13	6	19	-15	45
13	Sevilla	38	12	7	19	-14	43
14	Alavés	38	11	10	17	-12	43
15	Elche	38	10	13	15	-8	43
16	Levante	38	11	9	18	-14	42
17	Osasuna	38	11	9	18	-6	42
18	Mallorca	38	11	9	18	-10	42
19	Girona	38	9	14	15	-16	41
20	Oviedo	38	6	11	21	-34	29