Julián Álvarez has the most career goals - expected goals in the Champions League, with 8.91.

Interpreted as:

most goals minus xg by a player all-time

	NAME	G-xG	G	xG	Rating	M	MIN	START	G/M	A	G+A	PK	FK	SH	SOT	WOOD	TCH	TCH-BOX	OFF
1	Julián Álvarez J. Álvarez	8.91	18	9.09	7.60	31	1,838	20	0.58	7	25	1	2	64	36	2	994	106	2
2	Raphinha	6.64	16	9.36	7.56	28	2,114	25	0.57	13	29	0	0	90	36	4	1,403	135	9
3	Kylian Mbappé K. Mbappé	6.11	37	30.89	7.18	47	3,949	45	0.79	8	45	7	0	187	102	5	2,165	405	46
4	Karim Benzema K. Benzema	5.53	19	13.47	7.03	22	1,853	21	0.86	2	21	3	0	81	42	1	1,094	143	11
5	Christopher Nkunku C. Nkunku	5.09	10	4.91	7.64	13	1,093	12	0.77	2	12	0	0	32	19	0	628	76	6
6	Rodrygo	4.57	20	15.43	7.24	51	3,337	37	0.39	9	29	2	0	116	55	4	2,122	244	5
7	Phil Foden P. Foden	4.14	14	9.86	7.83	40	2,697	28	0.35	10	24	0	0	99	44	4	2,096	176	8
8	Giacomo Raspadori G. Raspadori	4.08	6	1.92	7.10	17	605	7	0.35	4	10	0	0	22	8	0	349	32	2
9	Bukayo Saka B. Saka	3.96	12	8.04	7.44	22	1,724	21	0.55	7	19	2	1	50	28	0	1,037	120	5
10	Robert Lewandowski R. Lewandowski	3.86	32	28.14	7.05	41	3,220	38	0.78	4	36	6	0	116	59	1	1,257	233	19
11	Cristiano Ronaldo C. Ronaldo	3.8	6	2.20		7	612	7	0.86	0	6	0	0	22	12	0	299	29	2
12	Felix Nmecha F. Nmecha	3.72	5	1.28	7.05	24	1,339	14	0.21	1	6	0	0	19	7	0	903	14	0
13	Roberto Firmino R. Firmino	3.63	7	3.37	6.94	15	740	6	0.47	1	8	0	0	18	9	0	532	46	1
14	Marcos Llorente M. Llorente	3.63	5	1.37	7.28	33	2,498	28	0.15	5	10	0	0	22	9	0	1,705	57	6
15	Désiré Doué D. Doué	3.6	7	3.40	7.41	17	756	9	0.41	3	10	0	0	34	19	2	584	53	4
16	Nuno Mendes N. Mendes	3.46	7	3.54	7.18	40	3,251	38	0.18	3	10	0	0	28	11	2	3,021	81	6
17	Christian Pulisic C. Pulisic	3.39	7	3.61	7.13	27	1,551	18	0.26	3	10	0	0	32	16	0	908	73	3
18	Bernardo Silva B. Silva	3.28	9	5.72	7.27	45	3,340	38	0.20	4	13	0	1	42	16	2	2,608	187	6
19	Harvey Elliott H. Elliott	3.16	5	1.84	7.20	14	607	6	0.36	0	5	0	0	15	9	0	471	28	0
20	Leroy Sané L. Sané	2.94	13	10.06	7.03	47	3,256	37	0.28	10	23	0	1	115	47	4	2,207	197	12
21	Karim Adeyemi K. Adeyemi	2.87	14	11.13	7.08	40	2,713	34	0.35	5	19	2	0	77	36	1	1,297	174	2
22	Weston McKennie W. McKennie	2.82	6	3.18	6.66	25	1,722	19	0.24	0	6	0	0	22	12	1	1,017	39	2
23	Luis Díaz L. Díaz	2.76	11	8.24	7.00	29	2,072	24	0.38	1	12	0	0	63	30	2	1,276	148	7
24	Couhaib Driouech C. Driouech	2.74	4	1.26	7.57	9	226	1	0.44	1	5	0	0	9	7	0	148	12	1
25	João Mário J. Mário	2.69	9	6.31	7.34	23	1,686	21	0.39	6	15	5	0	20	11	1	1,173	39	1