Answered January 12th, 2020

Since 1960, Brandon Guyer has the highest 100 * times getting hit-by-pitches per plate appearance when making 800+ plate appearances, with 5.72.

most 100*hbp/pa in a career 800 pa since 1960
Interpreted as:
most 100*hbp/pa by a player in a career 800 or more pa since 1960

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