I don't have anything for this season, but Ricardo Pepi and Ismael Saibari were tied for the most shots on target by a PSV player in the Champions League in 2025-26, with 6 shots on target.
| NAME | SOT | SEASON | CLUB | Rating | M | MIN | START | G | G/M | A | G+A | PK | FK | SH | WOOD | TCH | TCH-BOX | OFF | ||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 |  | R. Pepi | 6 | 2025-26 | 7.71 | 5 | 152 | 1 | 3 | 0.60 | 2 | 5 | 0 | 0 | 8 | 1 | 63 | 10 | 1 | |
| 2 |  | I. Saibari | 6 | 2025-26 | 6.89 | 7 | 603 | 7 | 3 | 0.43 | 0 | 3 | 0 | 0 | 15 | 0 | 327 | 27 | 6 | |
| 3 | | C. Driouech | 4 | 2025-26 | 7.38 | 7 | 197 | 1 | 3 | 0.43 | 2 | 5 | 0 | 0 | 9 | 0 | 106 | 13 | 1 | |
| 4 | | I. Perišić | 3 | 2025-26 | 6.05 | 8 | 533 | 7 | 1 | 0.13 | 1 | 2 | 1 | 0 | 11 | 0 | 315 | 19 | 3 | |
| 5 | | G. Til | 3 | 2025-26 | 6.66 | 8 | 578 | 7 | 2 | 0.25 | 3 | 5 | 0 | 0 | 7 | 0 | 201 | 16 | 2 | |
| 6 | | D. Man | 3 | 2025-26 | 6.98 | 8 | 456 | 6 | 2 | 0.25 | 0 | 2 | 0 | 0 | 7 | 0 | 263 | 15 | 1 | |
| 7 | | J. Veerman | 2 | 2025-26 | 6.74 | 8 | 720 | 8 | 0 | 0.00 | 1 | 1 | 0 | 0 | 7 | 0 | 711 | 2 | 0 | |
| 8 | | S. Dest | 1 | 2025-26 | 6.26 | 6 | 457 | 5 | 0 | 0.00 | 1 | 1 | 0 | 0 | 3 | 0 | 402 | 10 | 0 | |
| 9 | | P. Wanner | 1 | 2025-26 | 6.33 | 6 | 281 | 3 | 0 | 0.00 | 0 | 0 | 0 | 0 | 4 | 0 | 148 | 3 | 0 | |
| 10 | | Mauro | 1 | 2025-26 | 7.48 | 7 | 629 | 7 | 0 | 0.00 | 2 | 2 | 0 | 0 | 5 | 0 | 527 | 9 | 0 | |
| 11 | | R. van Bommel | 1 | 2025-26 | 8.82 | 1 | 90 | 1 | 1 | 1.00 | 0 | 1 | 0 | 0 | 2 | 1 | 46 | 3 | 0 |
PSVStatMuse has Champions League data for shots on target going back to the 2015-16 season.