Emilio Butragueño tallied the most non-penalty goals in LaLiga in 1990-91, with 19 non-penalty goals.

	NAME	NPG	SEASON	CLUB	M	MIN	START	G	G/M	PK
1	Emilio Butragueño E. Butragueño	19	1990-91	Real Madrid	35	3,042	35	19	0.54	0
2	Luis Enrique L. Enrique	15	1990-91	Sporting Gijón	35	2,495	27	15	0.43	0
3	Milan Luhový M. Luhový	14	1990-91	Sporting Gijón	31	2,391	28	16	0.52	2
4	Ernesto Valverde E. Valverde	13	1990-91	Athletic Club	36	2,891	33	13	0.36	0
5	José María Bakero J. María Bakero	13	1990-91	Barcelona	34	2,970	34	13	0.38	0
6	Manuel Sánchez M. Sánchez	13	1990-91	Atlético Madrid	37	2,943	35	16	0.43	3
7	Anton Polster A. Polster	13	1990-91	Sevilla	35	3,065	35	13	0.37	0
8	Jan Urban J. Urban	13	1990-91	Osasuna	34	2,992	34	13	0.38	0
9	Rommel Fernández R. Fernández	13	1990-91	Tenerife	31	2,549	29	13	0.42	0
10	Dalian Atkinson D. Atkinson	12	1990-91	Real Sociedad	29	2,532	29	12	0.41	0
11	Carlos Antonio Muñoz C. Antonio Muñoz	12	1990-91	Oviedo	36	3,092	36	12	0.33	0
12	John Aldridge J. Aldridge	12	1990-91	Real Sociedad	35	3,117	35	17	0.49	5
13	Hristo Stoichkov H. Stoichkov	12	1990-91	Barcelona	24	1,844	23	14	0.58	2
14	Julio Salinas J. Salinas	11	1990-91	Barcelona	33	1,954	21	11	0.33	0
15	Miguel Pardeza M. Pardeza	11	1990-91	Real Zaragoza	37	3,246	37	13	0.35	2
16	Pedro Alcañiz P. Alcañiz	11	1990-91	Castellón	32	2,743	31	11	0.34	0
17	Pepe Mel P. Mel	10	1990-91	Real Betis	31	2,427	27	14	0.45	4
18	Cuco Ziganda C. Ziganda	10	1990-91	Osasuna	37	3,034	34	11	0.30	1
19	Hugo Sánchez H. Sánchez	10	1990-91	Real Madrid	19	1,620	19	12	0.63	2
20	Gregorio Fonseca G. Fonseca	10	1990-91	Real Valladolid	37	3,153	36	14	0.38	4
21	Ricardo González Bango R. González Bango	9	1990-91	Oviedo	33	2,648	31	11	0.33	2
22	Iván Luis Zamorano I. Luis Zamorano	9	1990-91	Sevilla	29	2,429	28	9	0.31	0
23	Gavril Pele Balint G. Pele Balint	9	1990-91	Real Burgos	37	2,863	33	10	0.27	1
24	Claudio Barragán C. Barragán	8	1990-91	Mallorca	36	2,851	33	8	0.22	0
25	Fernando Hierro F. Hierro	7	1990-91	Real Madrid	35	3,026	33	7	0.20	0

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1	Barcelona	7	7	0	0	24	21
2	Atlético Madrid	7	5	1	1	9	16
3	Real Betis	7	5	1	1	2	16
4	Real Madrid	7	5	0	2	10	15
5	Sevilla	7	4	1	2	1	13
6	Alavés	7	3	2	2	5	11
7	Deportivo	7	2	4	1	2	10
8	Real Sociedad	7	3	1	3	-4	10
9	Villarreal	7	2	2	3	1	8
10	Athletic Club	6	2	2	2	1	8
11	Getafe	7	2	2	3	-3	8
12	Rayo	7	2	2	3	-5	8
13	Osasuna	7	2	2	3	-7	8
14	Celta Vigo	7	1	4	2	2	7
15	Espanyol	7	2	1	4	0	7
16	Racing	7	2	1	4	-10	7
17	Levante	6	1	2	3	-4	5
18	Elche	7	1	2	4	-6	5
19	Valencia	7	1	1	5	-9	4
20	Málaga	7	0	3	4	-9	3