Sidney Crosby won 45.5 percent of faceoffs in his rookie season in 2005-06.

NAME	SEASON	TM	GP	FOW%	G	A	P	+/-	PIM	PPG	PPA	SHG	SHA	GWG	OTG	S	S%	TOI/GP
Sidney Crosby	2005-06	PIT	81	45.5	39	63	102	-1	110	16	31	0	2	5	3	278	14.0	20:08
Sidney Crosby	2006-07	PIT	79	49.8	36	84	120	+10	60	13	48	0	0	4	0	250	14.4	20:46
Sidney Crosby	2007-08	PIT	53	51.4	24	48	72	+18	39	6	21	0	1	4	0	173	13.9	20:51
Sidney Crosby	2008-09	PIT	77	51.3	33	70	103	+3	76	7	33	0	1	3	1	238	13.9	21:57
Sidney Crosby	2009-10	PIT	81	55.9	51	58	109	+15	71	13	21	2	1	6	1	298	17.1	21:57
Sidney Crosby	2010-11	PIT	41	55.7	32	34	66	+20	31	10	9	1	0	3	0	161	19.9	21:55
Sidney Crosby	2011-12	PIT	22	50.1	8	29	37	+15	14	2	9	0	0	3	0	75	10.7	18:28
Sidney Crosby	2012-13	PIT	36	54.3	15	41	56	+26	16	3	14	0	0	1	0	124	12.1	21:06
Sidney Crosby	2013-14	PIT	80	52.5	36	68	104	+18	46	11	27	0	0	5	1	259	13.9	21:58
Sidney Crosby	2014-15	PIT	77	49.9	28	56	84	+5	47	10	21	0	0	3	1	237	11.8	19:58
Sidney Crosby	2015-16	PIT	80	51.7	36	49	85	+19	42	10	14	0	0	9	2	248	14.5	20:28
Sidney Crosby	2016-17	PIT	75	48.2	44	45	89	+17	24	14	11	0	0	5	1	255	17.3	19:53
Sidney Crosby	2017-18	PIT	82	53.0	29	60	89	0	46	9	29	0	0	6	3	247	11.7	20:41
Sidney Crosby	2018-19	PIT	79	55.4	35	65	100	+18	36	12	17	0	2	3	1	220	15.9	21:00
Sidney Crosby	2019-20	PIT	41	55.6	16	31	47	-8	15	4	13	0	0	4	2	109	14.7	20:16
Sidney Crosby	2020-21	PIT	55	53.6	24	38	62	+8	26	5	17	1	0	5	3	159	15.1	20:24
Sidney Crosby	2021-22	PIT	69	52.4	31	53	84	+19	32	8	22	0	0	9	1	208	14.9	19:58
Sidney Crosby	2022-23	PIT	49	52.5	24	36	60	+4	24	5	12	0	0	6	0	137	17.5	20:10

StatMuse has season-level data for faceoff win percentage going back to the 1999-00 season.