Fernando Morientes has tallied the most career goals in the Champions League with exactly 0 penalties scored, with 33 goals.

most goals without penalties by a player career

	NAME	G	PK	M	MIN	START	G/M	A	G+A	FK	SH	SOT	WOOD	TCH	TCH-BOX	OFF
1	Fernando Morientes F. Morientes	33	0	93	5,975	70	0.35
2	Álvaro Morata Á. Morata	29	0	89	5,056	57	0.33	8	37
3	Edin Džeko E. Džeko	29	0	75	5,580	65	0.39	10	39
4	David Trezeguet D. Trezeguet	29	0	58	4,087	46	0.50
5	Patrick Kluivert P. Kluivert	29	0	71	5,367	58	0.41
6	Ryan Giggs R. Giggs	28	0	145	10,554	122	0.19
7	Sadio Mané S. Mané	27	0	64	4,816	56	0.42	8	35	0	128	58	4	2,815	330	50
8	Raheem Sterling R. Sterling	27	0	88	5,749	62	0.31	19	46	0	133	67	3	3,248		39
9	Mario Gómez M. Gómez	26	0	44	2,585	27	0.59
10	Hernán Crespo H. Crespo	25	0	65	4,262	49	0.38
11	Giovane Élber G. Élber	25	0	69	5,095	58	0.36
12	Mário Jardel M. Jardel	25	0	46	3,739	40	0.54
13	José João Altafini J. João Altafini	24	0	28	2,016	22	0.86
14	Leroy Sané L. Sané	23	0	83	5,598	60	0.28	17	40	3	169	63	4	3,844		26
15	Roberto Firmino R. Firmino	22	0	56	3,452	37	0.39	13	35	0	103	43	4	2,244	256	8
16	Mario Mandžukić M. Mandžukić	21	0	60	4,514	52	0.35	1	22
17	Claudio Pizarro C. Pizarro	21	0	73	4,353	50	0.29	0	21
18	Carlos Alonso C. Alonso	21	0	46	3,719	42	0.46
19	Amancio Amaro A. Amaro	21	0	52	4,468	52	0.40
20	José Torres J. Torres	21	0	33	2,970	33	0.64
21	Phil Foden P. Foden	20	0	68	4,549	48	0.29	15	35	0	153	67	5	3,469	265	10
22	Pierre-Emerick Aubameyang P. Aubameyang	20	0	46	3,243	36	0.43	8	28
23	Gareth Bale G. Bale	20	0	66	4,434	49	0.30	9	29
24	Fernando Torres F. Torres	20	0	79	4,737	52	0.25	2	22
25	Paul van Himst P. van Himst	20	0	39	3,495	38	0.51