Cristiano Ronaldo has scored the most career penalties in LaLiga, with 61 penalties scored.

most penalty kick goals by a player without a miss in history

	NAME	PK	G	M	MIN	START	G/M	A	G+A
1	Cristiano Ronaldo C. Ronaldo	61	311	292	25,130	284	1.07	44	355
2	Lionel Messi L. Messi	60	474	520	42,168	464	0.91	106	580
3	Hugo Sánchez H. Sánchez	56	234	347	30,505	346	0.67
4	Ronald Koeman R. Koeman	46	67	192	15,916	177	0.35
5	Lyuboslav Mladenov Penev L. Mladenov Penev	43	129	305	24,997	286	0.42
6	Iago Aspas I. Aspas	40	164	383	29,891	338	0.43	55	219
7	Daniel Ruiz-Bazán D. Ruiz-Bazán	34	147	303	24,625	271	0.49
8	Rafael Carlos Marañón R. Carlos Marañón	34	115	308	24,918	271	0.37
9	Dani Parejo D. Parejo	33	77	521	40,999	464	0.15	66	143
10	David Villa D. Villa	32	184	352	27,285	319	0.52	4	188
11	Ander Garitano A. Garitano	31	50	381	27,628	315	0.13
12	Raúl Tamudo R. Tamudo	30	146	407	29,476	337	0.36
13	Roberto López R. López	30	112	418	34,890	391	0.27
14	Quini	30	217	448	35,821	397	0.48
15	Aitor Larrazabal A. Larrazabal	29	39	390	31,596	356	0.10
16	Míchel	28	97	404	33,676	377	0.24
17	László Kubala L. Kubala	28	138	215	19,350	215	0.64
18	Àngel Alonso À. Alonso	27	107	261	19,704	214	0.41
19	Germán Dévora G. Dévora	27	85	349	30,363	343	0.24
20	José Luis Zalazar J. Luis Zalazar	26	67	252	20,421	225	0.27
21	Mario Alberto Kempes M. Alberto Kempes	26	126	222	18,895	218	0.57
22	Karim Benzema K. Benzema	25	238	439	32,042	375	0.54	80	318
23	Juan Antonio Señor J. Antonio Señor	25	54	304	27,001	303	0.18
24	Juan Gómez J. Gómez	25	99	350	27,232	313	0.28
25	Manuel Torres M. Torres	25	56	192	17,280	192	0.29