Villarreal have a W5 D6 L13 record on the road in the Champions League all-time.

	CLUB	DATE	W-D-L		OPP	RESULT	W%	G	SH	SOT	PASS	PASS-ATT	POSS%	FOUL	YC	RC	SUBS
1	Villarreal	9/27/2005	W0 D1 L0	@	Lille	D 0-0	.000	0							2	0	3
2	Villarreal	11/2/2005	W1 D0 L0	@	Benfica	W 1-0	1.000	1							3	0	3
3	Villarreal	11/22/2005	W0 D1 L0	@	Man United	D 0-0	.000	0							3	0	3
4	Villarreal	2/22/2006	W0 D1 L0	@	Rangers	D 2-2	.000	2							3	0	3
5	Villarreal	3/29/2006	W0 D0 L1	@	Inter	L 1-2	.000	1							2	0	3
6	Villarreal	4/19/2006	W0 D0 L1	@	Arsenal	L 0-1	.000	0							5	0	3
7	Villarreal	9/17/2008	W0 D1 L0	@	Man United	D 0-0	.000	0							3	0	3
8	Villarreal	11/5/2008	W0 D1 L0	@	Aalborg	D 2-2	.000	2							3	0	3
9	Villarreal	12/10/2008	W0 D0 L1	@	Celtic	L 0-2	.000	0							4	1	2
10	Villarreal	3/10/2009	W1 D0 L0	@	Panathinaikos	W 2-1	1.000	2							1	0	3
11	Villarreal	4/15/2009	W0 D0 L1	@	Arsenal	L 0-3	.000	0							4	1	3
12	Villarreal	9/27/2011	W0 D0 L1	@	Napoli	L 0-2	.000	0							3	0	3
13	Villarreal	10/18/2011	W0 D0 L1	@	Man City	L 1-2	.000	1							4	0	3
14	Villarreal	11/22/2011	W0 D0 L1	@	Bayern	L 1-3	.000	1							3	0	3
15	Villarreal	9/29/2021	W0 D0 L1	@	Man United	L 1-2	.000	1	15	7	377	442	44.3	10	4	0	5
16	Villarreal	10/20/2021	W1 D0 L0	@	Young Boys	W 4-1	1.000	4	13	6	360	435	50.7	5	1	0	4
17	Villarreal	12/9/2021	W1 D0 L0	@	Atalanta	W 3-2	1.000	3	9	6	219	334	35.8	10	2	0	5
18	Villarreal	3/16/2022	W1 D0 L0	@	Juventus	W 3-0	1.000	3	8	3	380	449	41.7	5	0	0	4
19	Villarreal	4/12/2022	W0 D1 L0	@	Bayern	D 1-1	.000	1	4	1	204	294	32.0	8	2	0	3
20	Villarreal	4/27/2022	W0 D0 L1	@	Liverpool	L 0-2	.000	0	1	1	185	279	26.8	7	2	0	5
21	Villarreal	9/16/2025	W0 D0 L1	@	Tottenham	L 0-1	.000	0	10	0	285	353	42.0	13	3	0	5
22	Villarreal	11/5/2025	W0 D0 L1	@	Páfos	L 0-1	.000	0	18	5	478	547	59.2	13	2	0	5
23	Villarreal	11/25/2025	W0 D0 L1	@	Dortmund	L 0-4	.000	0	10	2	254	317	33.0	12	0	1	5
24	Villarreal	1/28/2026	W0 D0 L1	@	Leverkusen	L 0-3	.000	0	5	2	367	427	34.8	15	3	0	5
	Total		W5 D6 L13				.208	22					40.0		62	3	87