Jerry Rice has scored the most career total touchdowns when catching <10 interceptions, with 208 touchdowns.

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most career touchdowns with less than 10 interceptions
Interpreted as:
most career touchdowns by a player with less than 10 defensive interceptions
RiceSmithTomlinsonMossOwensAllenFaulkCarterHarrisonBrownPetersonPaytonFitzgeraldGatesRigginsMooreAlexanderGonzalezSandersBrownLargentGoreMartin208175162157156145136131128126125125121116116113112111109105101100100
NAMEGPTDINTTKLASTCOMBSCKSCKYINT YDSINT TDFFFRFR TD
Jerry RiceJerry Rice30320807070.0000101
Emmitt SmithEmmitt Smith22617506060.0000150
LaDainian TomlinsonLaDainian Tomlinson17016208080.0000090
Randy MossRandy Moss2181571260260.000080
Terrell OwensTerrell Owens2191560241250.000120
Marcus AllenMarcus Allen22214500.000151
Marshall FaulkMarshall Faulk17613609090.0000130
Cris CarterCris Carter23413104040.000061
Marvin HarrisonMarvin Harrison19012806060.000020
Jim BrownJim Brown11812600080
Adrian PetersonAdrian Peterson1831250201210.00000160
Walter PaytonWalter Payton19012500.000210
Larry FitzgeraldLarry Fitzgerald2631210410410.0000020
Antonio GatesAntonio Gates2361160240240.0000030
John RigginsJohn Riggins17511600.00080
Lenny MooreLenny Moore143113000151
Shaun AlexanderShaun Alexander12311204040.0000130
Tony GonzalezTony Gonzalez2701110250250.000050
Barry SandersBarry Sanders15310900.000130
Tim BrownTim Brown25510502020.0000120
Steve LargentSteve Largent20010100.00040
Frank GoreFrank Gore2411000140140.00000111
Curtis MartinCurtis Martin16810007180.0000130
Franco HarrisFranco Harris17310000.000150
Eric DickersonEric Dickerson1469600.000160
StatMuse has season-level data for interceptions going back to the 1940 season.