Lionel Messi has achieved the most career hat tricks in LaLiga with exactly 0 penalties scored, with 27 hat tricks.

most hattricks without penalties by a player in the world

	NAME	HT	PK	G	M	MIN	START	G/M	A	G+A	FK	SH	SOT	WOOD	TCH	TCH-BOX	OFF
1	Lionel Messi L. Messi	27	0	372	463	37,389	412	0.80	94	466
2	Telmo Zarra T. Zarra	21	0	235	270	24,300	270	0.87
3	Edmundo Suárez E. Suárez	18	0	192	227	20,430	227	0.85
4	Alfredo Di Stéfano A. Di Stéfano	16	0	198	315	28,350	315	0.63
5	Cristiano Ronaldo C. Ronaldo	14	0	197	237	20,262	229	0.83	39	236
6	César Rodríguez C. Rodríguez	12	0	187	335	30,150	335	0.56
7	Manuel Badenes M. Badenes	11	0	139	198	17,820	198	0.70
8	Pahiño	10	0	196	270	24,300	270	0.73
9	Isidro Lángara I. Lángara	10	0	89	84	7,560	84	1.06
10	Mariano Martín M. Martín	9	0	107	130	11,700	130	0.82
11	Marcelino Guillermo García M. Guillermo García	9	0	100	155	13,950	155	0.65
12	Guillermo Gorostiza G. Gorostiza	9	0	164	243	21,870	243	0.67
13	Agustín Sauto A. Sauto	9	0	108	118	10,620	118	0.92
14	Luis Suárez L. Suárez	8	0	155	245	19,214	217	0.63	67	222	1	744	357	32	9,256	1,205	292
15	Evaristo de Macedo E. de Macedo	8	0	81	130	11,700	130	0.62
16	Joaquín Murillo J. Murillo	8	0	121	220	19,800	220	0.55
17	Juan Arza J. Arza	8	0	172	340	30,600	340	0.51
18	Francisco Campos F. Campos	8	0	122	200	18,000	200	0.61
19	Manuel Alday M. Alday	8	0	66	79	7,110	79	0.84
20	Waldo Machado W. Machado	7	0	114	215	18,863	209	0.53
21	Ferenc Puskás F. Puskás	7	0	120	161	14,490	161	0.75
22	Joaquín Peiró J. Peiró	7	0	95	166	14,940	166	0.57
23	Adrián Escudero A. Escudero	7	0	134	276	24,840	276	0.49
24	Juan Araujo J. Araujo	7	0	139	207	18,630	207	0.67
25	José Juncosa J. Juncosa	7	0	115	232	20,880	232	0.50