Lionel Messi has achieved the most career hat tricks in the Champions League with exactly 0 penalties scored, with 7 hat tricks.

most hattricks without penalties by a player in the world

	NAME	HT	PK	G	M	MIN	START	G/M	A	G+A	FK	SH	SOT	WOOD	TCH	TCH-BOX	OFF
1	Lionel Messi L. Messi	7	0	102	146	12,056	133	0.70	19	121
2	Cristiano Ronaldo C. Ronaldo	6	0	110	166	14,284	161	0.66	19	129
3	Kylian Mbappé K. Mbappé	4	0	57	90	7,181	80	0.63	24	81	0	296	155	5	3,815	686	78
4	Karim Benzema K. Benzema	4	0	86	149	10,828	129	0.58	7	93
5	José João Altafini J. João Altafini	4	0	24	28	2,016	22	0.86
6	Ferenc Puskás F. Puskás	4	0	30	38	3,367	38	0.79
7	Neymar	3	0	38	78	6,639	75	0.49	26	64
8	Robert Lewandowski R. Lewandowski	3	0	75	127	10,320	119	0.59	11	86
9	Mario Gómez M. Gómez	3	0	26	44	2,585	27	0.59
10	José Torres J. Torres	3	0	21	33	2,970	33	0.64
11	Alfredo Di Stéfano A. Di Stéfano	3	0	41	55	4,946	55	0.75
12	Adriano	2	0	12	26	1,704	20	0.46
13	Didier Drogba D. Drogba	2	0	42	90	6,993	79	0.47	1	43
14	Michael Owen M. Owen	2	0	11	29	1,710	20	0.38
15	Samuel Eto'o S. Eto'o	2	0	27	76	5,922	67	0.36
16	Filippo Inzaghi F. Inzaghi	2	0	43	80	5,377	63	0.54
17	Andy Cole A. Cole	2	0	18	48	3,509	41	0.38
18	Andriy Shevchenko A. Shevchenko	2	0	45	97	7,975	91	0.46
19	Marco Simone M. Simone	2	0	23	46	2,965	31	0.50
20	Romário	2	0	19	31	2,682	30	0.61
21	Luc Nilis L. Nilis	2	0	17	42	3,048	35	0.40
22	Torbjörn Anders Nilsson T. Anders Nilsson	2	0	14	14	1,225	14	1.00
23	Anthony Blanker A. Blanker	2	0	8	3	241	3	2.67
24	Tamagnini Batista T. Batista	2	0	15	38	2,986	33	0.39
25	Denis Law D. Law	2	0	14	18	1,620	18	0.78