Vladimir Guerrero Jr. has the highest career OPS in the ALCS with 23+ at-bats, with an OPS of 1.330.

Interpreted as:

highest alcs ops by a player minimum 23 ab

	NAME	OPS	AB	SERIES	G	R	H	2B	3B	HR	RBI	BB	HBP	SO	SB	CS	PA	TB	XBH	SH	SF	IBB	GIDP	AVG	OBP	SLG
1	Vladimir Guerrero Jr. V. Guerrero Jr.	1.330	26	ALCS	7	6	10	3	0	3	3	4	1	2	0	0	31	22	6	0	0	3	0	.385	.484	.846
2	Tony Oliva T. Oliva	1.302	25	ALCS	6	5	11	4	0	2	3	1	0	4	1	0	26	21	6	0	0	0	0	.440	.462	.840
3	Adolis García A. García	1.293	28	ALCS	7	7	10	0	0	5	15	0	2	6	1	0	30	25	5	0	0	0	0	.357	.400	.893
4	Fred Lynn F. Lynn	1.273	29	ALCS	8	5	15	3	0	1	8	2	0	3	0	0	32	21	4	1	0	0	2	.517	.548	.724
5	Nelson Cruz N. Cruz	1.254	58	ALCS	16	14	19	6	0	8	20	7	1	12	0	1	66	49	14	0	0	1	2	.328	.409	.845
6	Enrique Hernández E. Hernández	1.254	26	ALCS	6	4	10	1	1	3	3	0	1	4	0	0	27	22	5	0	0	0	0	.385	.407	.846
7	Kevin Youkilis K. Youkilis	1.253	58	ALCS	14	14	24	4	1	5	13	7	0	7	0	0	65	45	10	0	0	0	3	.414	.477	.776
8	Evan Longoria E. Longoria	1.148	27	ALCS	7	8	7	3	0	4	8	3	0	5	0	0	30	22	7	0	0	0	3	.259	.333	.815
9	George Brett G. Brett	1.128	103	ALCS	27	22	35	5	4	9	19	11	0	9	0	3	115	75	18	0	1	3	2	.340	.400	.728
10	Paul Molitor P. Molitor	1.128	42	ALCS	11	11	15	3	1	3	10	5	1	6	1	1	48	29	7	0	0	1	1	.357	.438	.690
11	Todd Walker T. Walker	1.117	27	ALCS	7	5	10	1	1	2	2	1	1	2	0	0	29	19	4	0	0	0	0	.370	.414	.704
12	Josh Hamilton J. Hamilton	1.117	46	ALCS	12	10	15	5	0	4	12	9	0	8	3	0	57	32	9	0	2	6	1	.326	.421	.696
13	Miguel Cabrera M. Cabrera	1.115	58	ALCS	16	11	19	5	0	5	15	12	0	15	2	0	70	39	10	0	0	3	2	.328	.443	.672
14	Cal Raleigh C. Raleigh	1.105	25	ALCS	7	6	6	1	0	4	4	4	0	10	0	0	29	19	5	0	0	2	1	.240	.345	.760
15	Carlos Pena C. Pena	1.060	26	ALCS	7	8	7	1	0	3	6	6	0	7	1	0	32	17	4	0	0	1	1	.269	.406	.654
16	David Murphy D. Murphy	1.059	30	ALCS	11	10	10	3	1	1	5	7	0	6	1	0	37	18	5	0	0	3	0	.333	.459	.600
17	Rafael Devers R. Devers	1.053	37	ALCS	10	11	12	0	0	4	12	5	0	7	0	0	42	24	4	0	0	0	0	.324	.405	.649
18	Don Buford D. Buford	1.044	28	ALCS	7	6	10	1	1	1	4	7	0	1	0	1	36	16	3	0	1	0	0	.357	.472	.571
19	B.J. Upton	1.039	32	ALCS	12	8	9	1	0	4	11	4	0	11	2	0	37	22	5	0	1	0	0	.281	.351	.688
20	DJ LeMahieu	1.029	26	ALCS	6	6	9	1	0	2	3	3	0	2	0	0	29	16	3	0	0	0	0	.346	.414	.615
21	Jose Offerman J. Offerman	1.022	24	ALCS	5	4	11	0	1	0	2	1	0	3	1	0	25	13	1	0	0	0	1	.458	.480	.542
22	Ruben Sierra R. Sierra	1.017	47	ALCS	14	6	16	3	2	2	10	6	0	9	1	2	55	29	7	0	2	1	1	.340	.400	.617
23	Anthony Rizzo A. Rizzo	1.007	26	ALCS	9	3	9	2	0	1	4	4	2	6	0	0	32	14	3	0	0	1	0	.346	.469	.538
24	Julio Rodríguez J. Rodríguez	1.007	25	ALCS	7	5	6	1	0	3	6	5	0	10	0	0	30	16	4	0	0	0	2	.240	.367	.640
25	Alcides Escobar A. Escobar	.998	41	ALCS	10	9	16	3	1	1	7	1	2	3	0	0	46	24	5	0	2	0	0	.390	.413	.585

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StatMuse has game-level data for OPS and at-bats going back to the 1903 playoffs.

Some of the information used here was obtained free of charge from Retrosheet.

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