Hugo Mallo has made the most career appearances by a captain in LaLiga, with 205 appearances.

	NAME	M	MIN	START	G	G/M	A	G+A	PK	FK	SH	SOT	WOOD	TCH	TCH-BOX	OFF
1	Hugo Mallo H. Mallo	205	17,904	205	8	0.04	14	22	0	0	123	46	2	14,666	250	41
2	Koke	198	16,353	198	7	0.04	18	25	0	0	95	30	1	15,106	155	2
3	Dakonam Djené D. Djené	195	16,527	195	0	0.00	3	3	0	0	34	4	0	8,481	75	5
4	Jesús Navas J. Navas	170	14,250	170	2	0.01	21	23	0	0	83	24	3	11,756	261	20
5	Sergio Ramos S. Ramos	161	14,026	161	34	0.21	4	38	15	1	178	69	5	12,311	214	32
6	Mikel Oyarzabal M. Oyarzabal	159	12,827	159	52	0.33	29	81	21	1	288	120	7	5,991	579	81
7	Dani Parejo D. Parejo	158	13,647	158	34	0.22	25	59	21	7	182	82	9	12,612	114	7
8	Gaya	144	12,084	144	5	0.03	17	22	0	0	90	28	3	8,350	170	27
9	José Luis Morales J. Luis Morales	139	11,553	139	44	0.32	20	64	7	0	249	113	5	5,139	644	72
10	Muniain	138	11,112	138	21	0.15	21	42	1	2	157	69	3	7,626	308	13
11	Lionel Messi L. Messi	135	11,854	135	130	0.96	54	184	14	18	722	333	29	11,434	873	45
12	Joaquín	124	9,547	124	19	0.15	18	37	2	0	122	47	8	6,569	243	29
13	Antonio Raíllo A. Raíllo	123	10,915	123	8	0.07	5	13	0	0	94	25	1	6,946	181	11
14	Mario Gaspar M. Gaspar	122	10,673	122	4	0.03	9	13	0	0	98	26	2	7,785	187	4
15	Iago Aspas I. Aspas	110	9,174	110	43	0.39	20	63	13	1	274	122	6	5,402	500	43
16	Manu	107	9,251	107	7	0.07	2	9	1	0	95	25	4	5,193	136	18
17	Dani García D. García	103	9,020	103	1	0.01	2	3	0	0	60	8	0	6,292	6	0
18	Albiol	100	8,664	100	0	0.00	1	1	0	0	14	3	0	6,756	37	5
19	Molina	93	7,416	93	25	0.27	8	33	6	0	145	59	8	3,395	399	77
20	Gabi	90	7,642	90	1	0.01	4	5	0	0	47	9	1	6,930	7	2
21	Sergio Busquets S. Busquets	85	7,295	85	2	0.02	4	6	0	0	26	7	0	7,332	52	3
22	Javi López J. López	85	7,217	85	0	0.00	4	4	0	0	16	2	0	4,973	21	0
23	Oier	82	6,719	82	3	0.04	4	7	0	0	44	11	2	3,795	71	8
24	Xabi Prieto X. Prieto	81	6,684	81	14	0.17	14	28	3	0	61	31	2	4,427	163	16
25	David García D. García	77	6,681	77	4	0.05	1	5	0	0	53	7	0	4,344	89	1