Alfredo Di Stéfano had 5 hat tricks and 49 goals in 58 appearances for Real Madrid in the Champions League in his career.
| NAME | SEASON | CLUB | M | MIN | START | G | G/M | A | G+A | PK | FK | SH | SOT | WOOD | TCH | TCH-BOX | OFF | ||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 |  | A. Di Stéfano | 1955-56 |  Real Madrid | 7 | 630 | 7 | 5 | 0.71 | 0 | |||||||||
| 2 | | A. Di Stéfano | 1956-57 | Real Madrid | 8 | 720 | 8 | 7 | 0.88 | 1 | |||||||||
| 3 | | A. Di Stéfano | 1957-58 | Real Madrid | 7 | 630 | 7 | 10 | 1.43 | 2 | |||||||||
| 4 | | A. Di Stéfano | 1958-59 | Real Madrid | 7 | 626 | 7 | 6 | 0.86 | 0 | |||||||||
| 5 | | A. Di Stéfano | 1959-60 | Real Madrid | 6 | 540 | 6 | 8 | 1.33 | 0 | |||||||||
| 6 | | A. Di Stéfano | 1960-61 | Real Madrid | 2 | 180 | 2 | 0 | 0.00 | 0 | |||||||||
| 7 | | A. Di Stéfano | 1961-62 | Real Madrid | 10 | 900 | 10 | 7 | 0.70 | 0 | |||||||||
| 8 | | A. Di Stéfano | 1962-63 | Real Madrid | 2 | 180 | 2 | 1 | 0.50 | 0 | |||||||||
| 9 | | A. Di Stéfano | 1963-64 | Real Madrid | 9 | 810 | 9 | 5 | 0.56 | 0 | |||||||||
| Total | 58 | 5,216 | 58 | 49 | 0.84 | 3 |
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| CLUB | W | D | L | GD | PTS | |
|---|---|---|---|---|---|---|
1 |  Real Madrid | 6 | 0 | 0 | 11 | 18 |
2 |  Barcelona | 5 | 1 | 0 | 15 | 16 |
3 |  Villarreal | 4 | 1 | 1 | 7 | 13 |
4 |  Espanyol | 3 | 3 | 1 | 1 | 12 |
5 |  Elche | 2 | 4 | 0 | 3 | 10 |
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| Team | W | D | L | GD | PTS | |
|---|---|---|---|---|---|---|
| 1 |  Liverpool | 5 | 0 | 0 | 6 | 15 |
| 2 |  Arsenal | 3 | 1 | 1 | 8 | 10 |
| 3 |  Tottenham | 3 | 1 | 1 | 7 | 10 |
| 4 |  Bournemouth | 3 | 1 | 1 | 1 | 10 |
| 5 |  Crystal Palace | 2 | 3 | 0 | 4 | 9 |
| 6 |  Chelsea | 2 | 2 | 1 | 5 | 8 |
| Team | W | D | L | GD | PTS | |
|---|---|---|---|---|---|---|
| 1 | Real Madrid | 6 | 0 | 0 | 11 | 18 |
| 2 | Barcelona | 5 | 1 | 0 | 15 | 16 |
| 3 | Villarreal | 4 | 1 | 1 | 7 | 13 |
| 4 | Espanyol | 3 | 3 | 1 | 1 | 12 |
| 5 | Elche | 2 | 4 | 0 | 3 | 10 |
| 6 |  Athletic Club | 3 | 1 | 2 | 0 | 10 |
| Team | W | D | L | GD | PTS | |
|---|---|---|---|---|---|---|
| 1 |  Frankfurt | 1 | 0 | 0 | 4 | 3 |
| 2 |  PSG | 1 | 0 | 0 | 4 | 3 |
| 3 |  Sporting CP | 1 | 0 | 0 | 3 | 3 |
| 4 |  Club Brugge | 1 | 0 | 0 | 3 | 3 |
| 5 |  Union SG | 1 | 0 | 0 | 2 | 3 |
| 6 |  Bayern | 1 | 0 | 0 | 2 | 3 |
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